Phydeaux -> RE: carbon nuetral gasoline! (4/8/2014 11:24:25 AM)
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ORIGINAL: DomKen quote:
ORIGINAL: Phydeaux quote:
ORIGINAL: DomKen quote:
ORIGINAL: Phydeaux quote:
ORIGINAL: Tkman117 Plus if you know that this will require so much energy, would you enlighten us on their process of producing cost effective, carbon neutral fuel? [:D] Certainly. They aren't. Read the damn article. $3-$6 dollars a gallon is the government PR. Ten years away from perfecting the process. The reason this makes sense for the navy (they think) is so they don't need tankers transporting fuel. It shortens supply lines. It has *long* been possible to make gasoline from water. Go google the Sabatier or Bosch reactions. Once you have methane or methanol google Fischer-Tropsch on how to convert that to gasoline. The bottom line is that you have to have free hydrogen. Cost of free hydrogen (not that you'll understand this: 285.8 kj Produced by Sabatier 168 ish Net required... 80 Kj. Triple that, counting the substantial energy requirements for the Fischer-Tropsch process, the costs to circulate the water, the costs to elevate the feed stocks to the required temperatures. And if I were a betting man, I'd bet they were using ruthenium as catalysts for both processes. Not at $3 a gallon they aren't and they specifically said they are using an iron based catalyst. Why don't you read? LOL. Why can't you read? They are in fact, doing what I guessed they would do. Let me quote you: The reduction and hydrogenation of CO2 to form hydrocarbons is accomplished using a catalyst that is similar to those used for Fischer-Tropsch reduction and hydrogenation of carbon monoxide," adds Willauer. By modifying the surface composition of iron catalysts in fixed-bed reactors, NRL has successfully improved CO2 conversion efficiencies up to 60 percent. - See more at: http://www.nrl.navy.mil/media/news-releases/2012/fueling-the-fleet-navy-looks-to-the-seas#sthash.8zjs13Ug.dpuf Since you have no understanding, I'll simplify it for you. Increasing the conversion efficiency means you get more of the product you want, less of product you don't want. It doesn't change the energy requirement. The fact that they are reliant on surface composition means that they will be very susceptible to catalyst poisoning. When (if) you bother to read up on the sabatier process you will find that it uses a variety of catalysts - ruthenium, nickel, iron for example. So sure, I guessed ruthenium. Doesn't change the fact that the process - and the energy costs are as described. They are using a reverse osmosis process with an electron stripper. Since you persist in pretending you have a clue, lets do the math for you. Sea water has 100 mg/Ltr dissolved Co2. one liter of petrol weighs .737 kg. The proportion of weight of carbon, as opposed to hydrogen is roughly 76%. So call it .55 kg of carbon per liter of petrol. Using the efficiencies quoted in the book - they remove 92% of the CO2, and the unwanted by products are 25%. Meaning the useful conversion is 69%. .55 kg required /.69 = .8 kg Co2. So how much water does it take to process to make 1 liter of gas? 800g/.1g = 8000 liters of water to make one liter of gasoline. Ground breaking. Truly. An Arleigh Class destroyer on routine status burns 1000 gallons of oil an hour. Or 3700 liters an hour. So to provide fuel for one destroyer, for one hour, you need to process 29.6 million liters of seawater. Uh huh. Color me amazed. Truly. So Mr. Mathematician. Why don't you impress me and calculate the energy requirement to make that fuel? C'mon. Impress me. Except of course, you can't, can you. Since you don't actually understand chemical reactions, or how the second law of thermodynamics work. Who gives a shit about making fuel for destoyers? The Navy doesn't and I don't. The Navy intends to use this to make jet fuel for aircraft. They have these big ships called aircraft carriers with nuclear reactors that have a lot of excess power capacity. They would love to be able to use that power to reduce their need to rely on under way replenishment by very vulnerable tankers. I, personally, would think that further development of the process to get it viable for industrial use would mean the end of petroleum and natural gas extraction. We could store wind or solar as hydrocarbons and get around all the problems with batteries and the other problems people like you have been raising about renewables. The fact that it is good clean green tech just drives you nuts I know but do try to stop gnashing your teeth and rending your clothes and try to enjoy the moment. Oh thats fine, factless ken. Show me the energy requirements then to produce jet fuel for one jet fighter. But again you can't. No science. No knowledge. And so you have no credibility to judge the feasibility of a PR piece. So you have no way of judging whether the $3-$6 is feasible.
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